Enhancing ketones and syngas production by CO2-assisted catalytic pyrolysis of cellulose with the Ce–Co–Na ternary catalyst

Jiang, Haifeng; Liu, Haipeng; Dong, Jiaxin; Song, Jiaxing; Deng, Sunhua; Chen, Jie; Hong, Wenpeng

doi:10.1016/j.energy.2022.123799

Cited by 9 publications

(1 citation statement)

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“…Thus, the introduction of the iron component further enhanced the occurrence of the above reactions and then promoted the decomposition of ADs to generate ketones. In addition, the work of Jiang et al (2022) indicated that oxygen species on the catalyst surface participated in the ketylation of compounds during biomass pyrolysis. Based on the XRD results, the prepared iron-modified Ni-Co composite catalyst was mainly composed of metal oxides.…”

Section: Resultsmentioning

confidence: 99%

Ketones Production by Catalytic Pyrolysis of Cellulose Using Iron-Modified Ni-Co Composite Catalyst: Products Distribution, Behaviour and Bio-oil Characteristics

Jia

Lei

2023

Energy Exploration & Exploitation

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In this work, the iron-modified Ni-Co composite catalyst was synthesized, and its catalytic effect on product distribution, behaviour and liquid characteristics was deeply studied. The result showed that the synthesized catalyst significantly improved the pyrolysis behaviour of cellulose, and the decomposition of cellulose occurred earlier. The highest yield of liquid product was 56.79wt%, which was obtained by adding the NCF-6 catalyst. The optimal ratio of catalyst in the sample was 5%, and the optimal pyrolysis temperature was 530°C. The characteristics of liquid product showed the introduction of the synthesized catalyst enhanced the decomposition of anhydrosugars and significantly promoted the generation of ketones in the liquid. The highest content of ketones in the liquid was 25.12%. Further analysis showed that the selectivity of 2(5H)-Furanone in the liquid component was strongest. These works provided an effective way to produce ketone-rich bio-oil from biomass.

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Section: Resultsmentioning

confidence: 99%