Ensembles of microelectrodes: Digital simulation by the two-dimensional expanding grid method

Arrays of Screen‐Printed Graphite Microband Electrodes as a Versatile Electroanalysis Platform

“…This detection limit improvement occurs due to an increase of the faradaic to capacitive currents ratio [33,34] . Because of the importance of capacitive currents for electroanalysis the electric double layer capacitance of the microband electrodes was estimated from cyclic voltammetry experiments in a solution containing only supporting electrolyte, where no faradaic current was present [35] .…”

The cyclic and linear sweep voltammetry of regular and random arrays of microdisc electrodes: Theory

“…This requires a theoretical treatment of the situation, which for cyclic and linear sweep voltammetry has proved to be a particularly difficult problem. Although a number of methods have been reported, they have all possessed restrictions [8][9][10]. Only recently did Girault and co-workers [7] provide the first example of a microdisc array cyclic voltammetry simulation method that could deal with a wide range of parameters.…”

The cyclic and linear sweep voltammetry of regular arrays of microdisc electrodes: Fitting of experimental data

“…A critical factor in the design/ fabrication of regular microdisc arrays is the centreto-centre separation, d. This needs to be large enough to avoid the overlap of adjacent diffusion zones (shielding) but not too large as to result in inefficient use of space. Hence, the problem of modelling diffusion to microelectrode arrays has been studied extensively by a number of research groups [1][2][3][4][5][6][7][8][9].…”