“…The energy losses ∆ω = ω i − ω 1 , ω 2 , then correspond to the energy costs for the different arrangements of the electrons within the SOC t 2g orbitals. Even though RIXS has already been employed to study spin-orbit excitations in DP Ir 5+ systems, marginal inter-site hopping has had an undetectable effect on the RIXS spectra which could be interpreted by a bare atomic model [3,5,16,22]. In contrast, we here show using RIXS that enhancement in inter-site hopping due to close placement of Ir 5+ ions drives the 6H-iridates (Ba 3 M Ir 2 O 9 (M = Mg, Zn, Ca, and Sr)) into a regime where the effective SOC strength is weakened and the ground state deviates from non-magnetic singlets (Fig.…”