The statistical properties of photons are fundamental to investigating quantum mechanical phenomena using light. In multiphoton, two-mode systems, correlations may exist between outcomes of measurements made on each mode which exhibit useful properties. Correlation in this sense can be thought of as increasing the probability of a particular outcome of a measurement on one subsystem given a measurement on a correlated subsystem. Here, we show a statistical property we call "discorrelation", in which the probability of a particular outcome of one subsystem is reduced to zero, given a measurement on a discorrelated subsystem. We show how such a state can be constructed using readily available building blocks of quantum optics, namely coherent states, single photons, beam splitters and projective measurement. We present a variety of discorrelated states, show that they are entangled, and study their sensitivity to loss.Quantum optics is, at its core, the study of the distributions of photons in modes of the electromagnetic field. These distributions can exhibit fundamental physical features such as photon antibunching 1-3 and photon number squeezing 4,5 , which cannot be explained using classical assumptions about the photon distribution. When we consider the joint distribution of photons across multiple modes, further nonclassical phenomena emerge, such as the presence of nonclassical correlations in the number of photons measured in each mode [6][7][8][9][10][11][12][13][14][15] . For an ideal two-mode squeezed vacuum state, the number of photons in each mode is always equal-the outcome of photon-number measurements are completely correlated 16 . By contrast, when two indistinguishable photons are incident on different ports of a balanced beam splitter, bosonic bunching dictates that both photons will exit the same port 17 , such that photon number measurements are anti-correlated. Here we introduce discorrelation, in which the joint probability P n,n of measuring n photons in each mode is precisely zero for all n, but the marginal distributions P n are nonzero for all n. Discorrelation is distinct from correlation, anti-correlation, and decorrelation, extending our understanding of quantum correlations. It is an infinite-dimensional version of "exclusive correlations", here analysed as an effect of photon statistics rather than in the context of generalised Bell states 18 . In this work we show ways to generate discorrelated states using commonly available input states and standard quantum optical techniques, and analyse the entanglement properties and loss behaviour of these states.Correlation has been studied extensively in quantum optics in the context of communication, namely as a means to share common randomness between two parties [19][20][21][22][23][24][25] . In this context, discorrelation can be used to share unique randomness between parties, complementary to conventional quantum communication protocols. Unique randomness, where each party has a random number that is distinct from the other parties' ,...