Enthalpies of crystallisation of equilibrium solid phases occurring in the system KCl−KBr−H2O at 298.15 K

The comprehensive topological isomorphism of liquid–vapor, fusibility, and solubility diagrams in the proper sets of variables is proven with the aid of van der Waals equations of the shift in phase equilibrium. Analogues of Gibbs–Konovalov and Gibbs–Roozeboom laws are demonstrated in solubility diagrams of ternary and quaternary systems under crystallization of different types of solid solutions. For the demonstration, the quaternary reciprocal system K+,NH4+||Cl−,Br−−H2O and its ternary subsystems with modeling of the liquid phase within the framework of the classical Pitzer formalism are mainly used. An algorithm for calculating solubility equilibria in these systems is given.

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Enthalpies of crystallisation of equilibrium solid phases occurring in the system KCl−KBr−H2O at 298.15 K

Cited by 3 publications

References 4 publications

The Characteristics of the Mixed Crystals of the KCl-KBr-H2O System at 298 K

The Characteristics of the Mixed Crystals of the KCl-KBr-H2O System at 298 K

Thermochemical properties of some electrolytes aqueous solutions in binary and ternary systems at 298.15K

Topological Isomorphism of Liquid–Vapor, Fusibility, and Solubility Diagrams: Analogues of Gibbs–Konovalov and Gibbs–Roozeboom Laws for Solubility Diagrams

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