We present an investigation of the antilinear superoperators and their applications in studying higher-dimensional quantum systems. The antilinear superoperators are introduced and various properties are discussed. We study several crucial classes of antilinear superoperators, including antilinear quantum channels, antilinearly unital superoperators, antiunitary superoperators and the generalized Θ-conjugation. Then using the Bloch representation, we present a systematic investigation of the quantum geometric transformations of higher-dimensional quantum systems. By choosing different generalized Θ-conjugation, different metrics for the space of Bloch space-time vectors are obtained, including the Euclidean metric and Minkowskian metric. Then using these geometric structures, we investigate the entanglement distribution over a multipartite system restricted by quantum geometric invariance.