This paper is a very brief review of the method for analyzing the space and time dependent exergy and irreversibility fields in processes. It presents the basic equations, the method for their use, and three examples from the work of the author and his former graduate students: flow desiccation, combustion of oil droplets, and combustion of pulverized coal. Conclusions from this Second Law analysis are used to attempt process improvement suggestions. Abstract. This paper is av ery brief reviewo ft he method for analyzing the space and time dependent exergyand irreversibility fields in processes. It presents the basic equations, the method for their use, and three examples from the work of the author and his former graduate students: 1 flowdesiccation, combustion of oil droplets, and combustion of pulverized coal. Conclusions from this Second Lawanalysis are used to attempt process improvement suggestions. Law) analysis must be added to the conventional energy accounting analysis during the conception, analysis, development, and design of such systems. Most of this analysis is nowadays conducted on the system leveldevelopment, by evaluating the exergyv alues and changes of component input and output streams and energy interactions. While this can indeed identify the exergyd estruction in as ystem component, it does not deliver the detailed information about the specific process phenomena, often space and time dependent, which causes the exergyc hanges in it. The phenomena may include heat transfer,m ass transfer,fl uid mechanics, chemical and/or nuclear reactions, and the presence of fields such as gravitational, electric and magnetic. This type of detailed analysis, which we shall call "intrinsic", due in the second phase of system development, is invaluable in accelerating the evolution of the innovative systems needed to meet the difficult demands of the coming century,and is the focus of this paper.
Disciplines
Engineering | Mechanical Engineering
APERSONAL INTRODUCTIONAlthough the objectivesofexergyorentropyanalysis appear to be obvious, it is very noteworthy to recall that the most important and useful ones are: (1) identification of the specific phenomena/processes that have large exergyl osses or irreversibilities, (2) understanding why these losses occur,(3) evaluating howtheychange with anychanges in the process parameters and configuration, and (4) as ac onsequence of all these, suggestions on howthe process could be improved. Asurprisingly large fraction of the publications in this field deal only with (1) above,and are therefore of little use, at best.We start by presenting the basic field equations needed for the intrinsic exergyanalysis, briefly survey the state of the art, and present specific examples from our work on convective desiccation and on combustion of oil droplets and of pulverized coal.
THE EXERGY/ENTROPY PRODUCTION FIELD EQUATIONSThe general transient rigorous physico-chemical partial differential equations for computing the intrinsic irreversibilities and exergyd estruction ...