“…Nevertheless, the origin of carbonate mud remains enigmatic, reflecting a knowledge gap in carbon cycle fluxes and the interpretation of carbonate geochemical records. Much of the debate on the origin of carbonate mud has focused on two mechanisms: (1) primary precipitation of aragonite in the water column, whether via homogeneous precipitation (Cloud et al, 1962;Macintyre & Reid, 1992;Milliman et al, 1993;Shinn et al, 1989) or nucleated on suspended carbonate particles (Morse et al, 2003) or microbes (Robbins & Blackwelder, 1992;Yates & Robbins, 1998), and (2) postmortem disintegration and dispersal of the skeletons of calcifying organisms -particularly calcareous algae and foraminifera-into individual mud-sized carbonate particles (Broecker et al, 2000;Broecker & Takahashi, 1966;Debenay et al, 1999;Lowenstam, 1955;Nelsen & Ginsburg, 1986;Neumann & Land, 1975;Stockman et al, 1967). Both mechanisms conflict with geochemical observations of modern carbonate mud: radiocarbon data preclude water column precipitation (Broecker et al, 2000;Broecker & Takahashi, 1966), while Sr concentration data are inconsistent with algal production (Milliman et al, 1993).…”