Environmental Fate of Triasulfuron in Soils Amended with Municipal Waste Compost

Said‐Pullicino, Daniel; Gigliotti, Giovanni; Vella, Alfred J.

doi:10.2134/jeq2004.1743

Cited by 66 publications

(51 citation statements)

References 24 publications

(45 reference statements)

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“…The increase of DOMsorption was probably related to more hydrophobic properties of DOM extracted at high temperature. These values were larger than the sorption coefficients of 0.42 l kg -1 found by Janzen et al (1996) for water extracts of composts obtained by autoclaving, but lower than sorption coefficients (around 4 l kg -1 ) of hydrophobic fraction of DOM extracted from composts by Said-Pullicino et al (2004).…”

Section: Resultscontrasting

confidence: 64%

“…Ben-Hur et al (2003) found that atrazine sorption in soils decreased with small DOM concentrations, because of formation of stable interactions in solution with DOM; however, when DOM concentration increased, atrazine sorption also increased through sorption of DOM-atrazine complex. Increase of pesticide sorption capacity was also found when soil was treated with hydrophobic fractions of DOM coming from compost (Said-Pullicino et al 2004) or during co-sorption experiments of DOM and anilines (Flores-Cespedes et al 2006).…”

Section: Resultsmentioning

confidence: 80%

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Pesticide desorption from soils facilitated by dissolved organic matter coming from composts: experimental data and modelling approach

et al. 2010

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Dissolved organic matter (DOM) interaction with pesticides was examined studying the ability of DOM to desorb 8 pesticides previously sorbed to soil. DOM was originating from municipal waste composts at two maturity degrees, recovered at 20°C and by hot-pressurised subcritical water. Pesticide desorption depended on their previous sorption on soil. When sorption was low (K OC B 50, sulcotrione, metalaxyl), water was more efficient than DOM for desorption. On the contrary, when sorption was high (K OC C 2000, trifluraline), little effect of DOM was observed. For the moderately sorbed pesticides, DOM favoured pesticide desorption compared to water. For the lowest sorbed pesticides (K OC B 100), hysteresis was increased with larger proportions of DOM extracted with subcritical-water. Dissolved organic matter extracted from fresh-immature compost had larger capacity to mobilize the sorbed pesticides than the DOM from the mature compost. The pesticide desorption resulted from the positive and competitive interactions between pesticide, DOM and soil surfaces. These interactions were modelled considering separate partitioning coefficients. A general equation allowed the deduction of specific coefficients describing interactions in solution between pesticides and the non-sorbed fraction of DOM remaining in solution. This fraction was supposed to contain the most hydrophilic fraction of DOM and was able to interact with the most polar pesticide (amitrol). When pesticide hydrophobicity increased, the partitioning between pesticide and DOM decreased. Modelling the three-phase system (liquid, DOM and solid phases) pointed out that the solid phase played the most important role on pesticide behaviour through the sorption process of DOM and pesticides.

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Section: Resultscontrasting

confidence: 64%

Section: Resultsmentioning

confidence: 80%

Pesticide desorption from soils facilitated by dissolved organic matter coming from composts: experimental data and modelling approach

et al. 2010

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“…Organic matter effects may also be explained by a micellar catalysis model (Georgi et al, 2008). Furthermore, soil amendment with organic matter favors biodegradation and may hinder the effect of amendment on chemical hydrolysis reactions, as observed for triasulfuron by Said-Pullicino et al (2004). However, those authors evidenced that this sulfonylurea degradation through (bio)hydrolysis was slightly reduced by compost amendment.…”

Section: Hydrolysismentioning

confidence: 99%

Fate of Pesticides in Soils: Toward an Integrated Approach of Influential Factors

Chaplain¹,

Mamy²,

Vieublé-Gonod³

et al. 2011

Pesticides in the Modern World - Risks and Benefits

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“…The approach offers very sensitive hyperspectral fluorescence measurements with a high detection limit of FDOM compounds. In prior investigations, EEMS has been key in detecting metals [16], hormones [17], hydrocarbons [18], pesticides [19], surfactants, amino acid residues, proteins, and humic compounds that are part of dissolved organic matter [20]- [22]. Furthermore, spectra from EEMS have been shown to be a reasonable proxy and tracer for primary production and degradation of optically active compounds in natural waters [23]- [25].…”

Section: Introductionmentioning

confidence: 99%

Spectroscopic evidence of anthropogenic compounds extraction from polymers by fluorescent dissolved organic matter in natural water

Miranda

Trojzuck

Voß

et al. 2016

J. Eur. Opt. Soc.-Rapid Publ.

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FDOM is one of the most important carriers of anthropogenic compounds in natural waters. It can combine with environmental contaminants and polymers to form diverse chemical structures. To this end, here a microfluidic chip was designed for the analysis of these changes in fluorescent dissolved organic matter (FDOM) fingerprints due to thermal treatment and varying time intervals of exposure. Excitation Emission Matrix Spectroscopy (EEMS) approach was utilized to detect and identify the inherent compounds in sampled FDOM. Strong direct correlations were founded, Spearman rank correlation values (ρ = 0.85 at α = 0.1, n = 4) and linear correlation R 2 = 0.8359 were noted between thermal treatment pattern 2 and fluorescence intensity of samples. Materials, acrylic based glue and cyclic olefin copolymer (COC) polymer, used to design the microfluidic sensor were determined to possess unique spectral features in the ultraviolet to green spectrum using EEMS. The study therefore provides an insight on methods to identify contaminants in natural waters. This underlines the potential of optical sensors providing measurements at fast intervals, enabling environmental monitoring.

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Environmental Fate of Triasulfuron in Soils Amended with Municipal Waste Compost

Cited by 66 publications

References 24 publications

Pesticide desorption from soils facilitated by dissolved organic matter coming from composts: experimental data and modelling approach

Pesticide desorption from soils facilitated by dissolved organic matter coming from composts: experimental data and modelling approach

Fate of Pesticides in Soils: Toward an Integrated Approach of Influential Factors

Spectroscopic evidence of anthropogenic compounds extraction from polymers by fluorescent dissolved organic matter in natural water

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