The rate constant k obtained is a fixed value for one sample type; k decreased with the increase in Fe 2 O 3 content.The values of α increased significantly with the increase in the total surface area S T (i.e., a decrease in particle diameter) in different particle size distributions. It is discovered that α typically represents the Ca elution tendency. Additionally, the change in α is small with the change in the Fe 2 O 3 content. It is demonstrated that the developed kinetic model is valid for the analysis of Ca elution for samples with different particle size distributions.