The shift to electric transportation is crucial to fighting climate change. However, Germany’s goal of 15 million electric vehicles (EVs) by 2030 remains distant. Therefore, enhancing their economic viability is essential to promoting EV adoption. One promising option to increase the economics for the user is PV self-consumption optimization using smart charging EVs. Yet, more research is needed to explore the use case’s impacts on the German/European energy systems. Therefore, PV self-consumption optimization using EVs is integrated into an energy system model, assessing its impact on the energy system in 2030. For this purpose, the use case is modeled for different groups of people—personas—which are defined in a way that creates a diverse set of personas reflecting the distribution of different statistical values within Germany. The modified (dis)charging profiles are then aggregated and integrated into the energy system model. With a high implementation of PV self-consumption optimization in Germany in 2030, a positive system effect (with a system cost reduction of 53 million EUR/a) can be observed with a lower need for further storage and less curtailment of renewable energies (RES). Furthermore, the market values for RES increase by 0.7%, which fosters the integration of RES.