2014
DOI: 10.1002/cctc.201300881
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Enzymatic Decarboxylation—An Emerging Reaction for Chemicals Production from Renewable Resources

Abstract: ChemCatChem 2014, 6, 689 -701 689 CHEMCATCHEM MINIREVIEWS Scheme 2. Fermentative production of styrene derivatives. This approach is applicable for the conversion of endogenously produced phenylalanine (R = H) and tyrosine (R = OH).Scheme 3. In bicarbonate buffer, PAD from Lactobacillus plantarum catalyzes the stereoselective addition of water on the vinyl substituent. [8] Scheme 4. Variants of AMD from Bordetella bronchiseptica catalyze the asymmetric synthesis of both enantiomers of a-arylpropionates. Varian… Show more

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Cited by 57 publications
(43 citation statements)
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References 120 publications
(152 reference statements)
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“…Decarboxylases are increasingly used in organic synthesis, and mechanistic studies have attracted great interest . The information obtained here on the structures and energetics of the Bs PAD‐catalyzed reaction may help to further understand PAD‐type enzymes and to extend their biocatalytic applicability.…”
Section: Introductionmentioning
confidence: 97%
“…Decarboxylases are increasingly used in organic synthesis, and mechanistic studies have attracted great interest . The information obtained here on the structures and energetics of the Bs PAD‐catalyzed reaction may help to further understand PAD‐type enzymes and to extend their biocatalytic applicability.…”
Section: Introductionmentioning
confidence: 97%
“…In recent reviews, Chaiyen and coworkers [36] have summarized the most important biotransformations of plant derived phenolic compounds through esterification, decarboxylation, amination, halogenation, and hydroxylation reactions, while Sieber and coworkers have highlighted the importance of several decarboxylase enzymes to produce valuable chemicals from renewable resources [37]. Other relevant reviews dealing with enzymatic carboxylation reactions using CO 2 or HCO 3 − can be found in the literature [38][39][40][41].…”
Section: Concerning Item I) Wilkerson and Coworkersmentioning
confidence: 99%
“…In Figure 3.1, the pharmaceuticals felbinac: [4], losartan [5], valsartan [6], imatinib [7], the agrochemical boscalid [8], and liquid crystals for LCD screens [9] are some examples of important biaryls. Curiously, this approach is analogous to the enzymatic decarboxylation of carboxylic acids that occurs in living organisms [11]. This lack of atom and step economy makes these methods less attractive for industrial processes.…”
Section: Pd-catalyzed Versions 153mentioning
confidence: 99%