Researchers have debated whether methylammonium lead iodide (MAPbI 3 ), with a perovskite crystal structure, is ferroelectric and therefore contributes to the current−voltage hysteresis commonly observed in hybrid perovskite solar cells (PSCs). We thoroughly investigated temperature-dependent polarization, dielectric, and impedance spectroscopies, and we found no evidence of ferroelectric effect in a MAPbI 3 thin film at normal operating conditions. Therefore, the effect does not contribute to the hysteresis in PSCs, whereas the large component of ionic migration observed may play a critical role. Our temperature-based polarization and dielectric studies find that MAPbI 3 exhibits different electrical behaviors below and above ca. 45 °C, suggesting a phase transition around this temperature. In particular, we report the activation energies of ionic migration for the two phases and temperaturedependent permittivity of MAPbI 3 . This study contributes to the understanding of the material properties and device performance of hybrid perovskites.