2007
DOI: 10.1016/j.ijadhadh.2006.09.009
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Epoxy–amine/metal interphases: Influences from sharp needle-like crystal formation

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Cited by 45 publications
(34 citation statements)
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“…Consequently, epoxy Ar samples are now synthesized on Al foil (and silicone is banished from the glove box). The significant thickness of the polyepoxy coupons (1 mm) ensures that Al does not diffuse up to the free surface, since the measured interphases do not exceed 300 m [29].…”
Section: Resultsmentioning
confidence: 99%
“…Consequently, epoxy Ar samples are now synthesized on Al foil (and silicone is banished from the glove box). The significant thickness of the polyepoxy coupons (1 mm) ensures that Al does not diffuse up to the free surface, since the measured interphases do not exceed 300 m [29].…”
Section: Resultsmentioning
confidence: 99%
“…[35][36][37]. The ACDC pretreatment, which was used in the present work, develops an oxide layer with a needle like structure at the interface of primer and the metal organic complex is also thought to be giving a "fibre reinforced" interphase.…”
Section: Discussionmentioning
confidence: 99%
“…These include restricted polymer motion in the vicinity of a rigid substrate, the selective adsorption of resin components onto the metal surface, 3,4 local chemical gradients as a result of metal-induced catalysis of the cure or oxidation, [5][6][7] and variations in cross-linking density as a result of thermal gradients or the formation and diffusion of organometallic species into the polymer. [8][9][10][11] This ambiguity around interphase structures stems from a historical dearth of techniques capable of analyzing the buried region directly. Previously, a highly successful approach for thermoplastic polymers has been to investigate ultrathin films as an approximation of the interphase.…”
Section: Introductionmentioning
confidence: 99%