1985
DOI: 10.3891/acta.chem.scand.39a-0093
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Equilibrium and Structural Studies of Silicon(IV) and Aluminium(III) in Aqueous Solution. 11. Polysilicate Formation in Alkaline Aqueous Solution. A Combined Potentiometric and 29Si NMR Study.

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Cited by 55 publications
(39 citation statements)
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“…These efforts were based on potentiometric titrations as well as infrared, Raman and 29 Si NMR spectroscopy [11][12][13][14][15][16][17]. From these studies, it became clear that aqueous silicate solutions is a mixture of anions and that the distribution of various silicate species mainly depended on the SiO 2 :Na 2 O ratio, SiO 2 concentration, pH, temperature and aging.…”
Section: Introductionmentioning
confidence: 99%
“…These efforts were based on potentiometric titrations as well as infrared, Raman and 29 Si NMR spectroscopy [11][12][13][14][15][16][17]. From these studies, it became clear that aqueous silicate solutions is a mixture of anions and that the distribution of various silicate species mainly depended on the SiO 2 :Na 2 O ratio, SiO 2 concentration, pH, temperature and aging.…”
Section: Introductionmentioning
confidence: 99%
“…One study assumed only the monomer and the dimer, but it allowed all possible ionizations of each (Sef5iK et al, 1997). Most other modelers (Svensson et al, 1986;Caullet et al, 1989;Grenthe et al, 1992;Eikenberg et al, 1990;Sjoberg et al, 1985) have included higher polymeric species as well. This study has also included the higher polymers since it is more comprehensive.…”
Section: Solubilities In Neutr4l Salt Solutionsmentioning
confidence: 99%
“…Initially, the exact set of silicate species (Sjoberg et al, 1985) was selected for this study since the results comprise more than half of the data used in this study. The optimal parameter fits were obtained for the same formation constants.…”
Section: Solubilities In Neutr4l Salt Solutionsmentioning
confidence: 99%
“…Under highly basic conditions Si(IV) can form a wide range of monomeric and polymeric species ranging from simple monomers to cubic octamers (Sjoberg et al 1985;Svensson et al 1986). These, species, which often are highly charged, have also been shown to interact strongly with environmentally important species such as Sr and Eu (a trivalent actinide analog), thus increasing the solubility of the important solid phases of these elements [i.e., SrCO 3 (c) and Eu(OH) 3 ].…”
Section: Understanding the Formation Of Polymerized Species Under Extmentioning
confidence: 99%