Equilibrium magnetic moment configurations in magnetic nanoparticle films: Effects of anisotropy, dipolar interaction, and Zeeman energy

Abstract

The equilibrium configurations of films consisting of magnetic small particles in which the anisotropy energy tends to align the magnetic moments perpendicular to the film are studied by Monte Carlo simulations. The effects of anisotropy energy, dipolar interaction, and Zeeman energy due to an external applied magnetic field, which can either be perpendicular or parallel to the film, are considered. As the relative strength of the relevant interaction energies changes, the system exhibits a variety of different magnetic moment configurations. Due to the competition between the dipolar interaction energy and the anisotropy energy, it is found that an approximately antiferromagnetic alignment with moments oriented perpendicular to the film results when the anisotropy energy dominates; while an in-plane antiferromagnetic alignment results when the dipolar interaction energy dominates. Results obtained by a zero-temperature analysis based on energy minimization are found to be in qualitative agreement with results obtained by numerical simulations.

UV-cured transparent magnetic polymer nanocomposites

“…Actually, the magnitude of the magnetic response in the film containing core-shell NPOs is slightly lower than in the other film. This can be explained either by invoking a role of the silca-magnetite interface, where spin disorder at the surface of the magnetite core can be enhanced by the surrounding silica shell, or by considering that the individual magnetic moments of different magnetite NPs within the same silica shell can be antiferromagnetically coupled by dipolar interaction [28], decreasing the total apparent moment per core-shell nanoparticle. It is not possible to discard either model on the basis of a room temperature measurement alone;…”