“…In this paper, we have studied absorption and fluorescence spectra of four Sm 3+ doped zinc fluoride borophosphate glasses of the composition P 2 [24,25] approach has been applied for the f ↔ f transitions of the RE ion to evaluate Ω λ (λ = 2, 4, 6) parameters, which in turn have been used to calculate various radiative properties [26][27][28] like transition probability, branching ratio, radiative lifetime of the excited state and stimulated emission cross-section of various emission lines because in designing optical devices these data are essentially [29] required. Recently, Koppe [30] has used these radiative properties in developing LEDs highly useful in optical telecommunication for converting electrical pulses into optical pulses in the visible region.…”