Erratum: Heats of vaporization of hydrogen bonded substances

New Formula for the Hydrogen-Bonding Hansen Component of Methanol, Ethanol, andn-Propanol for Non-ambient Conditions—Application in Gas Antisolvent Fractionation-Based Optical Resolution

“…34 Pauling 34 discussed the hydrogen-bond strength for water and different alcohols and stated that onefifth of the energy contributions can be attributed to the van der Waals forces, and the rest represents the hydrogen-bond strength. Also, it was discussed that based on enthalpies of sublimation and formation of dimers, trimers, and tetramers, the hydrogen-bond energy contribution is in the range of 5000−6000 cal/mol in the case of water and aliphatic alcohols which agrees with the values given in the erratum of Bondi 35 (Table 5).…”

“…Bondi and Simkin used the experimental data from Rossini and Fiock to obtain E h parameters for different alcohols (including methanol, ethanol, and n -propanol) at different temperatures. The corrected data for methanol, ethanol, and n -propanol can be found in the erratum of Bondi and Simkin and are listed here in Table .…”

“…d E h /d T , as listed in Table , is the slope of the common regression line, fitted on the E h values of the different alcohols at different temperatures. In the studies of Bondi and Simkin, , the data are available for each alcohol and for a range of temperature, and thus, liquid-specific E h and d E h /d T values can be obtained for any temperature within the range.…”