Erratum: Quasi-two-dimensional magnetic correlations in 
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 probed by 
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Dioguardi, A. P.; Selter, S.; Peeck, U.; Aswartham, S.; Sturza, Mihai; Murugesan, R.; Eldeeb, Mohamed S.; Hozoi, Liviu; Büchner, B.; Grafe, H.-J.

doi:10.1103/physrevb.104.099901

Cited by 3 publications

(4 citation statements)

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“…To obtain the precise transition temperature, we calculated the derivative d𝜒/dT for susceptibility data shown in Figure 2 and used their peak position to define T N (Figure 4a), which has been widely used in previous studies. [41,54,56,59,72] The extracted T N values for the end compounds FePSe 3 , FePS 3 , and MnPSe 3 are 111.1, 120.1, and 73.4 K, respectively, consistent with the reported values. [28,30,43,53,59,64] As shown in Figures 4b and d , both Fe 1−x Mn x PSe 3 and FeP(Se 1−x S x ) 3 samples exhibit similar non-monotonic composition-dependent T N .…”

Section: Resultssupporting

confidence: 78%

“…It is worth noting that, though short-range magnetic correlations in the PM state should exist in all MPX 3 compounds, strong susceptibility anisotropy is not present in many other MPX 3 compounds such as MnPX 3 [35,37,59] and NiPX 3 . [27,54,59,72] This difference may be ascribed to the highly anisotropic Ising-type magnetism in FeP(Se 1−x S x ) 3 , the magnetic correlation of which causes significant magnetic susceptibility anisotropy above T N . The typical behavior for MnPX 3 and NiPX 3 has been attributed to their relatively weaker magnetic anisotropy.…”

Section: Resultsmentioning

confidence: 99%

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Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Basnet,

Patel,

Wang

et al. 2024

Adv Elect Materials

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Recent developments in 2D magnetic materials have motivated the search for new van der Waals magnetic materials, especially Ising‐type magnets with strong magnetic anisotropy. Fe‐based MPX3 (M = transition metal, X = chalcogen) compounds such as FePS3 and FePSe3 both exhibit an Ising‐type magnetic order, but FePSe3 receives much less attention compared to FePS3. This work focuses on establishing the strategy to engineer magnetic anisotropy and exchange interactions in this less‐explored compound. Through chalcogen and metal substitutions, the magnetic anisotropy is found to be immune against S substitution for Se whereas tunable only with heavy Mn substitution for Fe. In particular, Mn substitution leads to a continuous rotation of magnetic moments from the out‐of‐plane direction toward the in‐plane. Furthermore, the magnetic ordering temperature displays non‐monotonic doping dependence for both chalcogen and metal substitutions but due to different mechanisms. These findings provide deeper insight into the Ising‐type magnetism in this important van der Waals material, shedding light on the study of other Ising‐type magnetic systems as well as discovering novel 2D magnets for potential applications in spintronics.

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Section: Resultssupporting

confidence: 78%

Section: Resultsmentioning

confidence: 99%

Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Basnet,

Patel,

Wang

et al. 2024

Adv Elect Materials

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“…Magnetoelectric and spintronic devices have revolutionized the world of electronics and are predicted to have numerous breakthroughs in data processing speeds, high storage density, and efficient energy consumption. ,− Some of the most well-studied 2D magnetic materials are transition-metal thiophosphates of the formula M 2 P 2 S 6 , where M = Fe, Ni, and Mn. This thiophosphate family demonstrates a wide range of interesting structural and magnetic properties. − …”

Section: Introductionmentioning

confidence: 99%

Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li₂MP₂S₆ Where M = Fe and Co

et al. 2021

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Transition-metal thiophosphates and selenophosphates are layered systems with the potential for displaying twodimensional (2D) magnetic phenomena. We present the crystal structures and magnetic properties of two lithium transition-metal thiophosphates, Li 1.56 Co 0.71 P 2 S 6 and Li 2.26 Fe 0.94 P 2 S 6 . The previously unreported Li 1.56 Co 0.71 P 2 S 6 crystallizes in the trigonal space group P31m with lattice parameters a = 6.0193(6) Å and c = 6.5675(9) Å. The CoS 6 octahedra are arranged in a honeycomb lattice and form 2D layers separated by lithium cations. The previously solved Li 2.26 Fe 0.94 P 2 S 6 is isostructural to Li 1.56 Co 0.71 P 2 S 6 but displays site mixing between the Li + and Fe 2+ cations within the thiophosphate layer. Unusually, Li 1.56 Co 0.71 P 2 S 6 appears to have P 2 S 6 3− and not P 2 S 6 4− anions. We therefore term it a "noninnocent" anion because of the ambiguous nature of its oxidation state. Combined neutron diffraction and magnetization measurements reveal that both Li 1.56 Co 0.71 P 2 S 6 and Li 2.26 Fe 0.94 P 2 S 6 display magnetic anisotropy as well as no long-range magnetic order down to 5 K. In the iron thiophosphate, susceptibility indicates an effective moment of 5.44(3) μ B , which may be best described by an S + L model, where S = 2 and L = 2, or close to the free ion limit. In the cobalt thiophosphate, we found the effective moment to be 4.35(2) μ B , which would point to an S = 3 / 2 and L = 1 model due to octahedral crystal-field splitting.

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“…For an anisotropic magnetic material, three different components of NMR shift K(T) such as K iso (isotropic shift), K ax (axial shift), and K aniso (anisotropic shift), arising from a general hyperfine coupling tensor, can be determined from the observed experimental line shape. In this respect, the principal components K X , K Y , and K Z of tensor K(T) can be used to define [54,55]. The temperature dependence of the NMR shift scales with the magnetic susceptibility as K ax/iso (T ) = K 0 + (A ax/iso hf /N A μ B )χ spin (T ), where K 0 accounts for the temperature-independent chemical and orbital shift, A hf is the hyperfine coupling constant between 7 Li nucleus and Yb 3+ spins, μ B is the Bohr magneton and N A is the Avogadro number, respectively.…”

Section: Nmr Measurementsmentioning

confidence: 99%

Spin liquid state in a rare-earth hyperkagome lattice

et al. 2022

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Erratum: Quasi-two-dimensional magnetic correlations in Ni2P2S6 probed by P

Cited by 3 publications

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Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li₂MP₂S₆ Where M = Fe and Co

Spin liquid state in a rare-earth hyperkagome lattice

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Erratum: Quasi-two-dimensional magnetic correlations in Ni2P2S6 probed by P

Cited by 3 publications

References 0 publications

Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe3 for Potential 2D Magnet

Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe3 for Potential 2D Magnet

Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li2MP2S6 Where M = Fe and Co

Spin liquid state in a rare-earth hyperkagome lattice

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Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Understanding and Tuning Magnetism in Layered Ising‐Type Antiferromagnet FePSe₃ for Potential 2D Magnet

Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li₂MP₂S₆ Where M = Fe and Co