Inspired by the recent measurement of the ratio of B c branching fractions to J/ψπ + and J/ψμ + ν μ final states at the LHCb detector, we study the semileptonic decays of B c meson to the S-wave ground and radially excited 2S and 3S charmonium states with the perturbative QCD approach. After evaluating the form factors for the transitions B c → P, V , where P and V denote pseudoscalar and vector S-wave charmonia, respectively, we calculate the branching ratios for all these semileptonic decays. The theoretical uncertainty of hadronic input parameters are reduced by utilizing the light-cone wave function for the B c meson. It is found that the predicted branching ratios range from 10 −7 up to 10 −2 and could be measured by the future LHCb experiment. Our prediction for the ratio of branching fractionsis in good agreement with the data. For B c → V lν l decays, the relative contributions of the longitudinal and transverse polarization are discussed in different momentum transfer squared regions. These predictions will be tested on the ongoing and forthcoming experiments.