We have studied the interaction of metastable 4 He * 2 excimer molecules with quantized vortices in superfluid 4 He in the zero temperature limit. The vortices were generated by either rotation or ion injection. The trapping diameter of the molecules on quantized vortices was found to be 96 ± 6 nm at a pressure of 0.1 bar and 27 ± 5 nm at 5.0 bar. We have also demonstrated that a moving tangle of vortices can carry the molecules through the superfluid helium.