When designing a structure or engineering a component, it is crucial to use methods that provide fast and reliable solutions, so that a large number of design options can be assessed. In this context, the proper generalized decomposition (PGD) can be a powerful tool, as it provides solutions to parametric problems, without being affected by the “curse of dimensionality.” Assessing the accuracy of the solutions obtained with the PGD is still a relevant challenge, particularly when seeking quantities of interest with guaranteed bounds. In this work, we compute compatible and equilibrated PGD solutions and use them in a dual analysis to obtain quantities of interest and their bounds, which are guaranteed. We also use these complementary solutions to compute an error indicator, which is used to drive a mesh adaptivity process, oriented for a quantity of interest. The corresponding solutions have errors that are much lower than those obtained using a uniform refinement or an indicator based on the global error, as the proposed approach focuses on minimizing the error in the quantity of interest.