Error Sources in the Gas Chromatographic System

Mikkelsen, L.

doi:10.1093/chromsci/5.12.601

Cited by 18 publications

(4 citation statements)

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“…This “on-line” chromatographic method is the most interesting as it reduces the number of manipulations; however, the method is limited by the accuracy of the calibration procedures. The different calibration methods used in the literature are exponential dilution, , direct injection, , and diffusion cell procedures. , …”

Section: Experimental Methods For Low Vapor Pressure Measurementsmentioning

confidence: 99%

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)

et al. 2007

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An apparatus for very low vapor or sublimation pressure measurements (10-3 Pa) was designed and built. The principle of the apparatus is based on the saturation by the sample and by a standard compound of an inert gas flowing through a saturator and into a cold GC column used as a trap. This stage is followed by a chromatographic analysis consisting of increasing the temperature of the column. The originality of the present apparatus lies on the use of a supplementary line containing the standard compound. The study of the two substances is carried out simultaneously. This relative method allows reliable measurements of vapor or sublimation pressures. The apparatus was tested by the study of several alkanes. The experimental pressures are in a good agreement with the available literature data.

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Section: Experimental Methods For Low Vapor Pressure Measurementsmentioning

confidence: 99%

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)

et al. 2007

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“…A flow method was chosen for calibration of the FID (6) and a special micropump was designed and built for this purpose (5, 62). A flow calibration method minimizes wall adsorption, which frequently can cause serious errors 'in other calibration techniques, such as exponential dilution (29, 40), direct injection (43,45), and diffusion cell procedures (2,29). Additionally, concentration changes can be made rapidly.…”

Section: Choice Of Analytical Techniquementioning

confidence: 99%

Vapor pressure of normal paraffins ethane through n-decane from their triple points to about 10 mm mercury

Carruth¹,

Kobayashi²

1973

J. Chem. Eng. Data

132

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“…The analytical implications of this mode of readout were discussed as well as methods of choosing the base line for peak area integration. Mikkelsen's (471) treatment of the magnitude of the sources of error in GC includes both chemical and hardware effects. The recognition of poorly resolved peaks by differentiating the detector output was used for locating shoulders (332) in some cases, quantitative peak area calculations may be made (46).…”

Section: Readoutmentioning

confidence: 99%

Gas chromatography

Juvet¹,

Cram²

1970

Anal. Chem.

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Error Sources in the Gas Chromatographic System

Cited by 18 publications

References 0 publications

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)

Vapor pressure of normal paraffins ethane through n-decane from their triple points to about 10 mm mercury

Gas chromatography

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Error Sources in the Gas Chromatographic System

Cited by 18 publications

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A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C10, n-C24, n-C28)

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C10, n-C24, n-C28)

Vapor pressure of normal paraffins ethane through n-decane from their triple points to about 10 mm mercury

Gas chromatography

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Product

Resources

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A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)

A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10^-3 Pa): Vapor−Liquid Equilibria of n-Alkanes (n-C₁₀, n-C₂₄, n-C₂₈)