Online education has been in practice before COVID-19. However, COVID-19 pandemic has popularized online education. This study aims to explore the application of Process Virtualization Theory (PVT) in an e-learning process to gain new insights into the education context. Data was collected through an online survey from 362 university students in Pakistan. Results of the structural equational modeling indicate that eradication of digital divide can improve students’ engagement in virtual learning environments and thus entrench e-learning as a viable mode of education. Thus, this study has unfolded the understudied factor of digital divide in a developing country setting. To this end, the study underscored the threatening potential of digital divide to e-learning. Furthermore, the study has validated the notion of PVT theory that when a virtual process or a system reduces the need for sensory requirements, there are more chances of adoption. For educational institutions, the findings recommend incorporating offline learner-material and interaction capability (e.g., feedback) in their e-learning management system to promote students’ adoption of e-learning.