ESR study of coordination compounds of copper with 16-membered macrocyclic tetraaza ligands

The differences in complexation behaviour of two diastereomeric tetraazamacrocycles, meso (1) and racemic (2) 5,5,7,12,12,14-hexamethyl-l,4,8,1l-tetraazacyclotetradecane, are explained by different conformations in solution, 1 being one stable conformer of almost rigid structure while 2 shows higher conformational flexibility to avoid steric strain. The methods used were 'H and I3C NMR and molecular modelling.

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Approach to the conformational behaviour of tetraazamacrocycles in the solution state. NMR and molecular modelling studies

Boetzel

Failla

Finocchiaro

et al. 1995

Magnetic Reson in Chemistry

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ESR study of coordination compounds of copper with 16-membered macrocyclic tetraaza ligands

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Approach to the conformational behaviour of tetraazamacrocycles in the solution state. NMR and molecular modelling studies

Approach to the conformational behaviour of tetraazamacrocycles in the solution state. NMR and molecular modelling studies

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