Essential oil of Dysphania ambrosioides as a green corrosion inhibitor for mild steel in HCl solution

Daoudi, Walid; Aatiaoui, Abdelmalik El; Falil, Noureddine; Azzouzi, M. El; Berisha, Avni; Olasunkanmi, Lukman O.; Dagdag, Omar; Ebenso, Eno E.; Koudad, Mohammed; Aouinti, Abdelouahad; Loutou, Mohamed; Oussaid, Adyl

doi:10.1016/j.molliq.2022.119839

Cited by 64 publications

(11 citation statements)

References 70 publications

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“…Further beneficial parameters in corrosion studies are capacitance ( C dl ) and relaxation time ( τ ), which are expressed by Eqs. ( 2 ) and ( 3 ), respectively 36 , 42 , and their values are given in Table 1 . …”

Section: Resultsmentioning

confidence: 99%

Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media

Alimohammadi

Ghaderi

Ramazani

et al. 2023

Sci Rep

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Undoubtedly, metal corrosion is one of the most challenging problems faced by industries. Introducing corrosion inhibitors is a reasonable approach to protecting the metal surface. Due to environmental concerns and the toxicity of industrial organic corrosion inhibitors, researchers are continually exploring acceptable replacements. The current study focused on the application of Falcaria Vulgaris (FV) leaves extract to mitigate mild steel (MS) corrosion in a 1 M HCl environment. The polarization findings demonstrated that the corrosion current density decreased from 264.0 µA/cm2 (for the sample submerged in the blank solution) to 20.4 µA/cm2 when the optimal concentration of 800 ppm of FV leaves extract was added to the acid solution. Electrochemical impedance spectroscopy (EIS) analysis revealed an inhibition efficiency of 91.3% at this concentration after 6 h of immersion. It was determined by analyzing several adsorption isotherms that this corrosion inhibitor obeys the Frumkin isotherm. AFM, FE-SEM, and GIXRD surface analyses also supported the findings that adding FV leaves extract can reduce metal damage by adsorption on the metal surface.

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Section: Resultsmentioning

confidence: 99%

Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media

Alimohammadi

Ghaderi

Ramazani

et al. 2023

Sci Rep

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“…As seen in Figure 7, HOMO in the inhibitor molecules is positioned on one side of the ring containing O atoms, whereas LUMO is located on the opposite side of the ring, implying that these part of the molecule can are prone to electron tranfer to/from the metal's surface [49][50][51].…”

Section: Dftmentioning

confidence: 99%

“…This exchange of electrons consequently results in the generation of a protective organic layer that coats the surface of the metal and preserves it from corrosion [43,48,[52][53][54]. Electron acceptors, also called LUMOs, are parts of an inhibitor's structure that are responsible to take electrons from a surface with a lot of electron density, like the surface of a metal [47,49,50]. As a result of the exchange of lone pair electrons between heteroatoms (N and O) and the vacant iron d-orbital, which consequences in a moderate rise in surface absorption potential, it is presumed that adsorption on the surface of the metal will be signi cantly greater.…”

Section: Dftmentioning

confidence: 99%

“…When the heights are in the zone of 1-3.5 Å in range, it is thought to indicate a chemisorb able process. On the other hand, for physical adsorption, RDF peaks are expected to be present at distances larger than 3.5 Å [47][48][49][50][51].…”

Section: Monte Carlo and Molecular Dynamic Simulationsmentioning

confidence: 99%

“…I3>I1≈I2. The MD model of adsorption dynamics is generally acknowledged to be the more accurate of the two [40,42,43,45,50]. After several hundreds of ps of NVT simulation, it is clear that the inhibitors Figure 9 adopt a horizontal structure on one side of the molecule rings onto the metal surface and is substantially adsorbed onto the Fe surface.…”

Section: Monte Carlo and Molecular Dynamic Simulationsmentioning

confidence: 99%

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The Effect of new reduced form of Schiff-base Ligands on corrosion inhibition of API 5L in seawater

Jafari

Soltanolkottabi

Rezaeivala

et al. 2022

Preprint

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Three synthesized Schiff base named 2,2’- (((2,2-dimethylpropane-1,3-diyl)bis(azanediyl)bis(methylene)disphenol (I1), 4,4’- (((2,2-dimethylpropane-1,3-diyl)bis(azanediyl)bis(methylene)bis(2-methoxyphenol) (I2) and 6,6’- (((2,2-dimethylpropane-1,3-diyl)bis(azanediyl)bis(methylene)bis(2-methoxyphenol) (I3) were evaluated as corrosion inhibitors for API 5L grade B steel in the artificial seawater by electrochemical impedance, polarization and Quantum chemical calculations methods. The results showed that all three compounds act as good inhibitors for carbon steel, but the I3 has the best inhibition efficiency of about 58% at 1mg/L. The results of density functional theory method were consistent with the experimental results.

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Green Corrosion Inhibition of Mild Steel in 1.0 M HCl Using Myrtus Communis Essential Oil: Experimental and Theoretical Investigations

Chaouche,

Tiskar,

Amri

et al. 2024

ChemistrySelect

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This study investigates the green corrosion inhibition of mild steel in 1.0 M HCl using Myrtus communis essential oil (EOMC). Experimental and computational methods were combined to evaluate the corrosion inhibition effectiveness of EOMC. Weight loss measurements and electrochemical techniques, demonstrated that EOMC achieves a maximum corrosion inhibition efficiency of 94.81% at a concentration of 400 ppm of MCEO extract. The icorr significantly decreased from 983 µA/cm2 in the 1.0 M HCl solution to 51 µA/cm2 at 10−3 M, demonstrating the inhibitor's effectiveness. Polarization studies suggested mixed‐type inhibition, affecting both anodic and cathodic reactions, supported by changes in Tafel slopes. The Rct reached 462 Ω cm2 at 400 ppm of EOMC, enhancing the steel's protective capability. Higher temperatures increased the corrosion rate, with icorr values rising from 51 µA/cm2 at 298 K to 501 µA/cm2. Surface analysis using scanning electron microscopy coupled with energy‐dispersive X‐ray spectroscopy (SEM‐EDX) confirmed the formation of a protective layer on the steel surface in the presence of EOMC. Additionally, density functional theory (DFT) calculations and molecular dynamics (MD) simulations provided further insights into the adsorption behavior of the EOMC molecules on the MS surface, revealing that the inhibition process involves both physisorption and chemisorption mechanisms.

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Essential oil of Dysphania ambrosioides as a green corrosion inhibitor for mild steel in HCl solution

Cited by 64 publications

References 70 publications

Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media

Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media

The Effect of new reduced form of Schiff-base Ligands on corrosion inhibition of API 5L in seawater

Green Corrosion Inhibition of Mild Steel in 1.0 M HCl Using Myrtus Communis Essential Oil: Experimental and Theoretical Investigations

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