Using segmented concentric rings to produce a radial electric field, an initial trial experiment on ion mass separation in a magnetized plasma with low collisionality has been successfully carried out. With the increase in electric field or the decrease in magnetic field, the azimuthal flow velocity in the Xe plasma saturated and then it decayed due to the unconfined condition. On the other hand, the Ar plasma, whose mass is lighter than the Xe one, did not show this behavior in this operational region. These results are consistent with a particle orbit analysis and a simple calculation of the balances of forces.