From our work, significant progress has been made in understanding the degradation of cement-casing systems. The CO 2 degradation process was evaluated in specimens with a large interfacial defect, such as large annular spaces, voids and/or channels, which may be the result of a poor cementing job. From the experiments showing no interfacial defect, no signs of degradation were observed, while from experiments showing interfacial defect, both the cement and steel undergo significant degradation. In the well casing, the CO 2 -rich brine affects the steel phase, leaching Fe 2+ ions into solution and promoting FeCO 3 precipitation on the material surface, while on the cement sheath, two processes are occurring: (i) the portlandite dissolution and (ii) the cement carbonation process. Then, iron (Fe 2+ ) starts to migrate into the cement structure, compromising the material's self-healing and pore-blocking features, while calcium (Ca 2+ ) starts to compose the corrosion film from the formation of mixed carbonates (Fe x Ca y CO 3 ) so reducing the corrosion layer's protection. Finally, both ions (Ca 2+ and Fe 2+ ) become so abundant in the material vicinity that they may form calcium carbonate (CaCO 3 ) on the corrosion layer and iron carbonate (FeCO 3 ) in the cement matrix. Thus, from our results, the degradation mechanisms of the cement-casing system in CO 2 -rich brine was revised.