In CERA-20C, the T2m-SST ensemble relationships are changing on diurnal, seasonal and longer time-scales and also within regions. The T2m ensemble spread is much larger than the SST ensemble spread at high frequencies (3 h), normally with low correlations due to different time-scales of oceanic and atmospheric dynamics, showing the atmospherically driven variability of T2m. On monthly time-scales, the T2m spread is mostly slightly lower than the SST spread, with high correlations and strong coupling, reflecting the SST-forced variability. T2m-SST coupling is strongest where atmospheric and oceanic boundary layers are shallow, e.g. in the summer hemisphere, and weakest where the atmospheric boundary layer becomes deep, e.g. in the ITCZ region. As the twentieth century progresses, ensemble spreads decline, while T2m-SST coupling becomes stronger as both atmosphere and oceans are better constrained to observations. In the Tropics, strong ENSO-related variability is found in T2m-SST coupling as atmospheric convection centres move interannually to break the SST-dominated relationships.