The
goal of this paper is to enable three-dimensional (3D) printed
lightweight composite foams by blending hollow glass microballoons
(GMBs) with high density polyethylene (HDPE). To that end, lightweight
feedstock for printing syntactic foam composites is developed. The
blend for this is prepared by varying the GMB content (20, 40, and
60 volume %) in HDPE for filament extrusion, which is subsequently
used for 3D printing. The rheological properties and the melt flow
index (MFI) of blends are investigated for identifying suitable printing
parameters. It is observed that the storage and loss modulus, as well
as complex viscosity, increase with increasing GMB content, whereas
MFI decreases. Further, the coefficient of thermal expansion of HDPE
and foam filaments decreases with increasing GMB content, thereby
lowering the thermal stresses in prints, which promotes the reduction
in warpage. The mechanical properties of filaments are determined
by subjecting them to tensile tests, whereas 3D printed samples are
tested under tensile and flexure tests. The tensile modulus of the
filament increases with increasing GMB content (8–47%) as compared
to HDPE and exhibit comparable filament strength. 3D printed foams
show a higher specific tensile and flexural modulus as compared to
neat HDPE, making them suitable candidate materials for weight-sensitive
applications. HDPE having 60% by volume GMB exhibited the highest
modulus and is 48.02% higher than the printed HDPE. Finally, the property
map reveals a higher modulus and comparable strength against injection-
and compression-molded foams. Printed foam registered 1.8 times higher
modulus than the molded samples. Hence, 3D printed foams have the
potential for replacing components processed through conventional
manufacturing processes that have limitations on geometrically complex
designs, lead time, and associated costs.