The ternary Al-Ce-Si phase equilibria were investigated using X-ray diffraction (XRD) methods, metallography, scanning electron microscopy with energy-dispersive X-ray analysis (SEM/EDX) and wavelength-dispersive X-ray microanalysis, and differential thermal analysis (DTA). The focus was on the Al-rich corner and the phases in equilibrium with (Al). Key experiments were selected by preliminary thermodynamic calculations. A consistent thermodynamic description was developed using the Calphad method incorporating all experimental data. A thermodynamic assessment for the binary Ce-Si system was also performed. Two ternary phases, Ce(Si 1Ϫx Al x ) 2 ( 1 ) and AlCeSi 2 ( 2 ), were confirmed. The phase Al 2 CeSi 2 ( 4 ) was sporadically observed, but is apparently metastable. The earlier reported phase Al 4 Ce 3 Si 6 could not be confirmed. In addition, the enthalpy of solidification of five Al-rich ternary alloys was measured in a differential scanning calorimetry (DSC) heat flux calorimeter. The agreement with the thermodynamic enthalpy calculations is acceptable. The fundamental intricacies involved in calculating a "latent" heat for alloys with a freezing range are pointed out. Various phase diagrams of the Al-Ce-Si system were calculated based on the thermodynamic description. They were used to quantitatively identify possible contributions to the grain refinement potential of Ce in Al-Si alloys due to the phase equilibria.