1984
DOI: 10.1016/0040-6031(84)85035-2
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Estimation des enthalpies de vaporisation des composes organiques liquides. Partie 4. Application aux composes organometalliques

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Cited by 16 publications
(5 citation statements)
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“…65 Higher-order models for these properties have been proposed by Benson, 51 Constantinou and Gani, 52 Marrero and Gani. 53 Kolska et al, 66 developed higher-order GC-models for enthalpies of vaporization and entropies of vaporization at 298 K as well as at the normal boiling point of the compound and compared their models with other GC-models [67][68][69][70][71] for the same properties. All these models can be represented by eqn (7), although the groups sets for each model are different.…”
Section: 21mentioning
confidence: 99%
“…65 Higher-order models for these properties have been proposed by Benson, 51 Constantinou and Gani, 52 Marrero and Gani. 53 Kolska et al, 66 developed higher-order GC-models for enthalpies of vaporization and entropies of vaporization at 298 K as well as at the normal boiling point of the compound and compared their models with other GC-models [67][68][69][70][71] for the same properties. All these models can be represented by eqn (7), although the groups sets for each model are different.…”
Section: 21mentioning
confidence: 99%
“…In a series of papers which appear to have been long neglected, Ducros et a/. [38][39][40][41] have shown that group additivity can be applied to a series of compounds to estimate AVH°298> whence it is possible to estimate AfH°(g). For hydrocarbons, average deviations are the order of 0.1 kcal/mol.37'39 For alcohols, which would be expected to provide a severe test because of their structural hydrogen bonding, average deviations are about 0.2 kcal/mol.38 For the halides, nitriles, and other monofunctionalized organics, the authors chose an algebraic formula to represent the effect of chain length on primary-, secondary-, and tertiary-substituted carbons.…”
Section: Use Of Liquid-phase Data To Obtain Gas-phase Enthalpiesmentioning
confidence: 99%
“…In Table are presented relevant data for a number of organic, regular liquids. The values of Δ vap H °(298) are calculated from group additivity using a modified choice of group values as will be discussed later, while values of 〈Δ vap C p °〉 are calculated with the use of eq 9.…”
Section: Heat Of Formation and Entropy Of Liquids At Their Boiling Po...mentioning
confidence: 99%
“…, the deviations are AAD ) 0.3 ( 0.12 cal/(mol K). The largest deviations are 1.2 cal/(mol K) for Ti Cl 4 and CH 2 -CCl 2 and 1.9 cal/(mol K) for WF6 . The estimated values of 〈∆ vap C p °〉 for a number of the compounds such as CH 2 Cl 2 , 39 cal/(mol K); CH 2 CCl 2 , 5 cal/(mol K); and WF 6 , 0 cal/(mol K) must be considered unreliable and a result of their very low boiling points.…”
mentioning
confidence: 92%
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