Sodium-water reaction (SWR) in a steam generator of sodium-cooled fast reactor (SFR) is a significant phenomenon for safety assessment of the system. One of the top concerns in the SWR is an overheating rupture phenomenon in which a neighbor heat transfer tube fails instantaneously because of a deterioration of structural integrity under a high temperature condition. Hence, the heat transfer coefficient on the tube surface is of importance. Since hydrogen gas is generated in the SWR and liquid water will evaporate quickly due to depressurization, the reaction region is covered with a multi-phase flow structure, and thus the value of the heat transfer coefficient will vary widely. In the present paper, a correlation diagram has been developed between the heat transfer coefficient and the void fraction based on one dimensional homogeneous flow simulation. Furthermore, the transient of void fraction in SWAT-1R experiment is investigated using the diagram.