The spectral analysis of Gaussian linear time-series processes is usually based on uni-frequential tools because the spectral density functions of degree 2 and higher are identically zero and there is no polyspectrum in this case. In finite samples, such an approach does not allow the resolution of closely adjacent spectral lines, except by using autoregressive models of excessively high order in the method of maximum entropy. In this article, multi-frequential periodograms designed for the analysis of discrete and mixed spectra are defined and studied for their properties in finite samples. For a given vector of frequencies !, the sum of squares of the corresponding trigonometric regression model fitted to a time series by unweighted least squares defines the multi-frequential periodogram statistic IM(!). When ! is unknown, it follows from the properties of nonlinear models whose parameters separate (i.e., the frequencies and the cosine and ORDER REPRINTS sine coefficients here) that the least-squares estimator of frequencies is obtained by maximizing I M (!). The first-order, second-order and distribution properties of I M (!) are established theoretically in finite samples, and are compared with those of Schuster's uni-frequential periodogram statistic. In the multi-frequential periodogram analysis, the least-squares estimator of frequencies is proved to be theoretically unbiased in finite samples if the number of periodic components of the time series is correctly estimated. Here, this number is estimated at the end of a stepwise procedure based on pseudo-F likelihood ratio tests. Simulations are used to compare the stepwise procedure involving I M (!) with a stepwise procedure using Schuster's periodogram, to study an approximation of the asymptotic theory for the frequency estimators in finite samples in relation to the proximity and signal-to-noise ratio of the periodic components, and to assess the robustness of I M (!) against autocorrelation in the analysis of mixed spectra. Overall, the results show an improvement of the new method over the classical approach when spectral lines are adjacent. Finally, three examples with real data illustrate specific aspects of the method, and extensions (i.e., unequally spaced observations, trend modeling, replicated time series, periodogram matrices) are outlined.Key Words: Trigonometric regression; Nonlinear models whose parameters separate; Least-squares estimation of frequencies; Finite-sample properties of periodogram statistics and frequency estimators; Analysis of discrete and mixed spectra 1064 DUTILLEUL