2016
DOI: 10.3762/bjoc.12.234
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Et3B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols

Abstract: A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita–Baylis–Hillman (MBH) alcohols, using Et3B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity.

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Cited by 4 publications
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“…107 Rezgui's group developed a method for C-C bond formation from β-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols using Et 3 B as a Lewis acid promoter in the presence of palladium catalyst. 108 A new protocol for direct benzylation/allylation of malonates with alcohols via palladium catalyzed Tsuji-Trost type reactions has been described.…”
mentioning
confidence: 99%
“…107 Rezgui's group developed a method for C-C bond formation from β-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols using Et 3 B as a Lewis acid promoter in the presence of palladium catalyst. 108 A new protocol for direct benzylation/allylation of malonates with alcohols via palladium catalyzed Tsuji-Trost type reactions has been described.…”
mentioning
confidence: 99%