Ether derivatives – Efficient Fe(III) extractants from HCl solution

Wojciechowska, Irmina; Wieszczycka, Karolina; Wojciechowska, Aleksandra; Aksamitowski, Przemysław

doi:10.1016/j.seppur.2018.08.048

Cited by 11 publications

(4 citation statements)

References 15 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…However, these resins do not have a significant adsorption capacity, while the regeneration of efficient chelating resins requires a strong acid desorbing agent, such as 4 M HCl in the case of glycidyl methacrylate-based polymer resins [ 13 ] or 1 M HNO 3 in the case of cross-linked polyzwitterionic acid [ 14 ]. In the presented research, the precursors of the pyridinium moieties that were introduced onto the polymer surface are N -decyloxy-1-(pyridnyl)ethanimines with high potential as metal extractants from neutral and acidic aqueous solutions (Fe(III) from HCl [ 15 ], Cu(II) and Cu(I) from chloride and sulfate solution [ 16 , 17 , 18 ], Pb(II) from acidic chloride–nitrate solution [ 19 , 20 ], and Zn(II) from HCl solution [ 21 ]). These compounds show exceptionally high metal ion removal efficiency in liquid–liquid and membrane systems [ 22 , 23 ].…”

Section: Introductionmentioning

confidence: 99%

Poly(vinylbenzyl Pyridinium Salts) as Novel Sorbents for Hazardous Metals Ions Removal

et al. 2022

Self Cite

View full text Add to dashboard Cite

Novel efficient complexing resins—poly(vinylbenzyl pyridinium salts) fabricated through poly(vinylbenzyl halogene-co-divinylbenzene) quaternization of N-decyloxy-1-(pyridin-3-yl)ethaneimine and N-decyloxy-1-(pyridin-4-yl)ethaneimine—were tested as adsorbents of Pb(II), Cd(II), Cu(II), Zn(II), and Ni(II) from aqueous solutions. The structure of these materials was established by 13C CP-MAS NMR, X-ray photoelectron spectroscopy, elemental analysis, and Fourier transform infrared spectroscopy, as well as thermogravimetric and differential thermal analyses. The textural properties were determined using scanning electron microscopy and low-temperature N2 sorption. Based on the conducted sorption studies, it was shown that the uptake behavior of the metal ions towards novel resins depended on the type of functionalities, contact time, pH, metal concentrations, and the resin dosage. The Langmuir model was investigated to be the best one for fitting isothermal adsorption equilibrium data, and the corresponding adsorption capacities were predicted to be 296.4, 201.8, 83.8, 38.1, and 39.3 mg/g for Pb(II), Zn(II), Cd(II), Cu(II), and Ni(II), respectively. These results confirmed that owing to the presence of the functional pyridinium groups, the resins demonstrated proficient metal ion removal capacities. Furthermore, VBBr-D4EI could be successfully used for the selective uptake of Pb(II) from wastewater. It was also shown that the novel resins can be regenerated without significant loss of their sorption capacity.

show abstract

Section: Introductionmentioning

confidence: 99%

Poly(vinylbenzyl Pyridinium Salts) as Novel Sorbents for Hazardous Metals Ions Removal

et al. 2022

Self Cite

View full text Add to dashboard Cite

show abstract

“…Tertiary amines [19,20] and imines [21] are also effective for the extraction of iron(III) from chloride solutions. Quaternary ammonium bases, for example, Aliquat 336 (a mixture of 3-octyl-and 3-decylamine chlorides) was used to extract iron(III) from a chloride solution after leaching of poor iron ores.…”

Section: Introductionmentioning

confidence: 99%

Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone

Sokolov

Valeev

Kasikov

2021

Metals

View full text Add to dashboard Cite

Research into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol with a ketone by an extraction mixture in relation to its effectiveness was investigated. The iron(III) was efficiently extracted by the mixture of 1-octanol and 1-decanol (70%) with 2-undecanone (30%) from hydrochloric bauxite leach liquor at an O:A ratio = 2-4:1 at an iron(III) concentration of 7.4 g/L and 6 M HCl. For the removal of iron-containing organic phase from impurities (Al, Ca, Cr) that are co-extracted with iron(III), we used two step scrubbing at O:A = 5:1 by 7 M HCl as a scrub solution. The iron(III) stripping at the O:A ratio is shown. Using counter-current cascade of extractors, it was possible to obtain an FeCl3 solution with the iron(III) content of 90.5 g/L and total impurities less than 50 mg/L.

show abstract

“…In Wieszczycka’s team, the search for advanced new extractants has resulted in the synthesis of pyridine derivatives containing an N -alkoxyimidamide or alkaneimine moieties (e.g., N -decoxy-1-(pyridin-3-yl)ethaneimine) [ 18 , 19 ], which have been reported to reach very fast equilibrium achieving in the extraction of Zn(II) or Fe(III) from chloride media. Good extraction properties of these derivatives for heavy metals made us investigate the use of quaternary salts of these derivatives, i.e., 3-[1-(2-ethylhexyloxyimine)methane]-1-propylpyridinium chloride, 3-[1-(decyloxyimine)methane ]-1-propylpyridinium chloride, 3-[1-(decyloxyimine)ethane]-1-propylpyridinium chloride and 4-[1-amine(2-ethylhexyloxyimine)]-1-propylpyridinium chloride towards Pd(II) and Pt(IV) recovery from chloride solutions.…”

Section: Introductionmentioning

confidence: 99%

“…Hence, the novelty of the investigation lies in the use of new extractants in the PGM model system. Based on the results for precursors of these quaternary salts [ 19 ] and looking for efficient extractants of PGM ions, it has been assumed that a type of substituent at imine nitrogen and/or the structure of substituent alkyl chain in the studied quaternary salts could influence the efficiency of Pd(II) and Pt(IV) extraction. Thus, in this work are presented preliminary results of the effect of extraction conditions such as hydrochloric acid concentration, type of metal ions, Pd(II) or Pt(IV), the structure of the pyridinium cation, and the extractant concentration.…”

Section: Introductionmentioning

confidence: 99%

Recovery of Palladium(II) and Platinum(IV) in Novel Extraction Systems

Wiecka¹,

Rzelewska-Piekut²,

Wojciechowska³

et al. 2021

Materials

Self Cite

View full text Add to dashboard Cite

Recovery of platinum group metals (PGM) from complex aqueous solutions generated as a result of leaching of various spent materials (e.g., spent automotive converters) is a vital issue in the context of the circular economy. In this study pyridinium derivatives containing an imidoamide or imine moiety (i.e., 3-[1-(2-ethylhexyloxyimine)methane]-1-propylpyridinium chloride, 3-[1-(decyloxyimine)methane]-1-propylpyridinium chloride, 3-[1-(decyloxyimine)ethane]-1-propylpyridinium chloride and 4-[1-amine(2-ethylhexyloxyimine)]-1-propylpyridinium chloride) are proposed as novel extractants for recovery of palladium(II) and platinum(IV) from model chloride aqueous solutions. The results of liquid-liquid extraction from one-component solutions of palladium(II) or platinum(IV) showed that quaternary pyridinium salts can be used as effective extractants for platinum metal ions. Moreover, PGM extraction from a two-component mixture proved no evident selectivity in the transfer of one of the metal ions to the organic phase. As the best extractant among the investigated ones, D3EI-PrCl (with straight alkyl chain at substituent) can be pointed out, however, problems with effective stripping or phase disengagement after stripping should be indicated as a drawback of the organic phases used. Further investigation should focus on the improvement of the organic phase properties (e.g., increase in hydrophobicity of the extractants and addition of an organic phase modifier) towards stripping efficiency.

show abstract

Ether derivatives – Efficient Fe(III) extractants from HCl solution

Cited by 11 publications

References 15 publications

Poly(vinylbenzyl Pyridinium Salts) as Novel Sorbents for Hazardous Metals Ions Removal

Poly(vinylbenzyl Pyridinium Salts) as Novel Sorbents for Hazardous Metals Ions Removal

Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone

Recovery of Palladium(II) and Platinum(IV) in Novel Extraction Systems

Contact Info

Product

Resources

About