In Houston, Texas, nitrogen dioxide (NO2)
air pollution
disproportionately affects Black, Latinx, and Asian communities, and
high ozone (O3) days are frequent. There is limited knowledge
of how NO2 inequalities vary in urban air quality contexts,
in part from the lack of time-varying neighborhood-level NO2 measurements. First, we demonstrate that daily TROPOspheric Monitoring
Instrument (TROPOMI) NO2 tropospheric vertical column densities
(TVCDs) resolve a major portion of census tract-scale NO2 inequalities in Houston, comparing NO2 inequalities based
on TROPOMI TVCDs and spatiotemporally coincident airborne remote sensing
(250 m × 560 m) from the NASA TRacking Aerosol Convection ExpeRiment–Air
Quality (TRACER-AQ). We further evaluate the application of daily
TROPOMI TVCDs to census tract-scale NO2 inequalities (May
2018–November 2022). This includes explaining differences between
mean daily NO2 inequalities and those based on TVCDs oversampled
to 0.01° × 0.01° and showing daily NO2 column-surface
relationships weaken as a function of observation separation distance.
Second, census tract-scale NO2 inequalities, city-wide
high O3, and mesoscale airflows are found to covary using
principal component and cluster analysis. A generalized additive model
of O3 mixing ratios versus NO2 inequalities
reproduces established nonlinear relationships between O3 production and NO2 concentrations, providing observational
evidence that neighborhood-level NO2 inequalities and O3 are coupled. Consequently, emissions controls specifically
in Black, Latinx, and Asian communities will have co-benefits, reducing
both NO2 disparities and high O3 days city wide.