1982
DOI: 10.1016/0009-2614(82)83539-2
|View full text |Cite
|
Sign up to set email alerts
|

ETS study of the negative ion states of t-butyl and trimethylsilyl derivatives of ethylene and benzene

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

9
92
0

Year Published

1986
1986
2007
2007

Publication Types

Select...
6

Relationship

3
3

Authors

Journals

citations
Cited by 108 publications
(101 citation statements)
references
References 16 publications
9
92
0
Order By: Relevance
“…The ET spectroscopy apparatus was in the format devised by Sanche and Schulz, [30] as has been described previously. [31] Microanalyses were performed by M-H-W Laboratories (Phoenix, AZ) and at the Centro de Investigaciones Químicas, Universidad Autó noma de Hidalgo (Pachuca, Hgo., Mexico). Analytical thin-layer chromatography was performed using E. Merck silica gel 60 F 254 coated plates (0.25 mm), and spots were visualized using long-and short-wavelength UV lamps.…”
Section: Resultsmentioning
confidence: 99%
“…The ET spectroscopy apparatus was in the format devised by Sanche and Schulz, [30] as has been described previously. [31] Microanalyses were performed by M-H-W Laboratories (Phoenix, AZ) and at the Centro de Investigaciones Químicas, Universidad Autó noma de Hidalgo (Pachuca, Hgo., Mexico). Analytical thin-layer chromatography was performed using E. Merck silica gel 60 F 254 coated plates (0.25 mm), and spots were visualized using long-and short-wavelength UV lamps.…”
Section: Resultsmentioning
confidence: 99%
“…The VAE of the Ł NC MOs of aliphatic isonitriles is higher than those of CO (1.5 eV) 30 and N 2 (1.89 eV), 31 being in the range 2.69-2.77 eV, similar to CH 3 NC (2.81 eV). 24 In aromatic isonitriles the out-of-plane Ł NC orbital mixes with the  Ł b 1 orbitals of the phenyl ring. This lowers the corresponding VAE considerably, i.e.…”
Section: Discussionmentioning
confidence: 99%
“…24 To enhance the visibility of the sharp resonance structures, the impact energy of the electron beam is modulated with a small a.c. voltage, and the derivative of the electron current transmitted through the gas sample is measured directly by a synchronous lock-in amplifier. The present spectra were obtained by using the apparatus in the 'high-rejection' mode 25 and are, therefore, related to the nearly total scattering cross-section.…”
Section: Methodsmentioning
confidence: 99%
See 2 more Smart Citations