“…Field‐scale nutrient studies in tile‐drained agroecosystems have evolved over the past 50 yr and now focus on methodologies for continuous monitoring of flow‐weighted mean concentrations (FWMCs) of dissolved and total nutrient species using automated samplers on surface flumes and subsurface tile mains (Harmel et al., 2018; Williams et al., 2016). Temporal and economic constraints often limit analyses that can be performed on samples, and, as a result, most long‐term monitoring programs typically only analyze bioavailable nutrients (orthophosphate, nitrate, and ammonium) and total nutrient concentrations (Christianson et al., 2016; Macrae, English, Schiff, & Stone, 2007; Macrae et al., 2019; Reba et al., 2013; Williams et al., 2016). Regarding total nutrients, both alkaline and alkaline/acid persulfate digestions on unfiltered samples have been used for coupled measurements of total P (TP) and total N (TN), although the alkaline persulfate digestions are recognized to underpredict TP when suspended sediment concentrations are significant (Dayton, Whitacre, & Holloman, 2017; Koroleff, 1983; Patton & Kryskalla, 2003).…”