The paper presents the results of laboratory-instrumental studies of atmospheric air sampled during the first day after fire suppression in different localization. Carbon oxide, hydrochloride, hydrocyanide, nitrogen oxides, sulfur dioxide, and dioxins were determined in the air samples taken. The comparison was made with the hygienic standards established by SanPiN 1.2.3685-21 “Hygienic standards and requirements to ensure safety and (or) harmlessness for humans of environmental factors”. Analysis of the obtained data showed that the concentrations of most of the detected toxic combustion products one day after fire suppression were at a level close to MAC for the working area air, but significantly exceeded MAC established for the atmospheric air of urban and rural settlements. The largest exceedances were obtained at sites such as industrial and residential buildings, which can be explained by the use of a wide range of building materials.