Evaluation of derivative normal pulse polarography for use in metal speciation studies

Evans, Otis M.; Hanck, Kenneth W.

doi:10.1016/s0003-2670(01)84121-0

Analytica Chimica Acta

1981

DOI: 10.1016/s0003-2670(01)84121-0

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Evaluation of derivative normal pulse polarography for use in metal speciation studies

Otis M. Evans

Kenneth W. Hanck

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1983

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Cited by 2 publications

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Faradaic response in derivative and differential normal pulse voltammetry

Lovric¹,

O’Dea²,

Osteryoung³

1983

Anal. Chem.

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A.; Fleischmann, M.; Thlrsk, H. R. Trans. Faraday SOC. 1962, Flelschmann, M.; Thirsk, H. R. 119. 73-91. Flelschmann, M.; Thirsk, H. R. Electrochim. Acta 1964, 9 , 757-771. Armstrong, R. D.; Fieischmann, M.; Thlrsk, H. R. Trans. Faraday SOC. 1965, 61, 2238. Thlrsk, H. R.; Harrison, J. A. "A Qulde to the StudyThe peak-shaped voltammograms arising from differentlal pulse, dlfferentiai normal pulse, and normal pulse dlfference modes of pulse voltammetry are compared for reversible systems and for systems wlth heterogeneous charge transfer control. The effects of variatlon of klnetlc parameters, k, and a, and the dependence on experlmental parameters of time and potentlal are examlned. For the reverslble case the current-potentlal curves are the same for the appropriate choke of experlmentai parameters. For quasi-reverslble cases the differences depend strongly on klnetlc parameters. Maxlmum differences are obtalned for the totally Irreversible case. The dlfferences between the differential normal pulse and normal pulse difference currents are less slgniflcant than the striking relatlve dlmlnutlon of the differential pulse response for irreversible systems.

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Faradaic response in derivative and differential normal pulse voltammetry

Lovric¹,

O’Dea²,

Osteryoung³

1983

Anal. Chem.

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Determination of pertechnetate by liquid chromatography with reductive electrochemical detection

Lewis¹,

Zodda²,

Deutsch³

et al. 1983

Anal. Chem.

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Evaluation of derivative normal pulse polarography for use in metal speciation studies

Cited by 2 publications

References 20 publications

Faradaic response in derivative and differential normal pulse voltammetry

Faradaic response in derivative and differential normal pulse voltammetry

Determination of pertechnetate by liquid chromatography with reductive electrochemical detection

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