Determination of 14 C, 55 Fe, 63 Ni and gamma emitters in two different types of activated reactor pressure vessel (RPV) steel samples were carried out. The gamma emitters were analysed using HPGe detectors with ISOCS and standard geometry calibrations. Two radioanalytical procedures for the 14 C, 55 Fe, 63 Ni analysis were developed using inactive samples and activated samples were analysed using modified procedures. A Monte Carlo code was used for the modelling of the activation results. The obtained measured and calculated results were comparable.