Evaluation of Gallium Arsenide Thermal Expansion Coefficient by Extended X-Ray Absorption Fine Structure

Abstract

Negative thermal expansion of gallium arsenide has been investigated through temperature dependent Extended X-ray Absorption Fine Structure (EXAFS) measurements. The bond thermal expansion coefficient bond α has been evaluated and compared to negative expansion coefficient tens α due to tension effects. The overall thermal expansion coefficient is the sum of bond α and tens α. Below 60 K, tens α is greater than bond α yielding to a negative expansion in this temperature region. Tension effects are progressively overcome by the stretching effects in the region 60-300 K. The asymmetry of nearest neighbors distribution is not negligible since the gaussian approximation underestimates the bond expansion by about 0.00426 Å. This error decreases when the temperature is lowered. The accuracy in the thermal expansion evaluation and the connection between third cumulant and thermal expansion are discussed.