This paper presents experimental and theoretical studies of heat transfer through single- and double-glazed windows with electrical heating of the internal surfaces. Heating is achieved by applying a voltage to the low emissivity coating of the inner glass. A thermophysical model has been developed to simulate the heat transfer through these units, allowing us to determine their thermal characteristics. Experimental data are used to validate the numerical model. The resulting heat flux and temperature distributions on the external and internal surfaces of electrically heated double-glazed units are analysed. According to the results of experimental and numerical studies, it was found that the adopted electric heating scheme allows 83–85% of the heat to enter the room and 15–17% is removed to the outside. This makes it possible to increase the radiation component of the heat flow from the window to the room and improve the thermal comfort in the room. In general, this article shows that existing industrial windows with low-emissivity glass surface coating can be upgraded with simple and inexpensive modernisation, without compromising the main function of the window—efficient transmission of visible light—and create an additional (backup) heating device that can work effectively together with the existing heating system in the event of a sudden cold snap at low temperatures (below −20 °C), to prevent condensation of water vapour in the windows, and to prevent condensation on the surface of the window facade wall. Formally, a back-up (emergency) heating system is created in the room, which contributes to the energy sustainability of the building and therefore to energy security in general.