This chapter discussed the object oriented finite element (OOF2)-based studies for ceramic composites. OOF2 is an effective method that uses an actual microstructure image of the material/composites for simulation. The effect of filler inclusions on the thermomechanical properties (coefficient of thermal expansion, thermal conductivity, Young’s modulus, stress and strain) is discussed. For this purpose, various ceramics composites (thermal barrier coating and ferroelectric based) are considered at homogeneous and heterogeneous temperature/stress conditions. The maximum stress is found at the interface of the filler/matrix due to their mismatch of thermal expansion coefficient. Further, residual and localized interface stress distributions are evaluated to analyze the composite’s failure behavior. The possible integration of OOF2 with other simulation techniques is also explored.