One-dimensional (1D) nanoarray structures exhibit an
electroporation
effect at low voltages and are capable of transiently inactivating
the passing bacteria, which is promising for air purification. However,
the sterilization effect of electrode materials in current air filtration
devices remains and needs further improvement owing to their low electron
transfer efficiency and limited yield of reactive oxygen species (ROS).
In this paper, we report the design of S-NiCo2O4 nanoneedles with hollow structures that exhibit superior antibacterial
effects against both Gram-negative and Gram-positive bacteria at lower
AC voltage and could be applied to air purification as an instantaneous
sterilization device. Due to the hollow structure and the sulfur doping,
the local electric field strength and ROS yield of S-NiCo2O4 were significantly increased. The results show that
the inactivation rate of E. coli and S. aureus reached 99.9%, and 99.8% at a low AC voltage
of 12 V and an air flow rate of 0.5 m/s. More importantly, through
finite element simulation, the effects of hollow structure and curvature
radius on the local electric field strength are analyzed, which in
turn improve the electroporation effect. The experimental results
also demonstrated that the increased active sites from S-doping led
to remarkable growth in the ROS yield of the S-NiCo2O4 nanoneedles and further improved the sterilization efficiency.