Directly photopatternable interfaces
are introduced that facilitate
two-dimensional spatial control of block copolymer (BCP) orientation
in thin films. Copolymers containing an acid labile monomer were synthesized,
formulated with a photoacid generator (PAG), and coated to create
grafted surface treatments (GSTs). These as-cast GST films are either
inherently neutral or preferential (but not both) to lamella-forming
poly(styrene-block-trimethylsilylstyrene) (PS-b-PTMSS). Subsequent contact printing and baking produced
GSTs with submicron chemically patterned gratings. The catalytic reaction
of the photoacid generated in the UV-exposed regions of the GSTs changed
the interfacial interactions between the BCP and the GST in one of
two ways: from neutral to preferential (“N2P”) or preferential to neutral (“P2N”). When PS-b-PTMSS was thermally annealed between a chemically patterned
GST and a top coat, alternating regions of perpendicular and parallel
BCP lamellae were formed.