Hydrochloric (HCl) crosslinked gelled acid systems have been extensively used in acid fracturing and matrix acidizing to help achieve acid diversion during stimulation treatments. These systems also help control fluids leakoff and help retard the acid reaction to allow deeper acid penetration. Currently, many in-situ crosslinked gelled acid systems generally consist of polymers, an iron crosslinker, and a breaker agent, in addition to other additives. This paper discusses an alternative crosslinker that provides effective diversion with minimal residuals at temperatures up to 275°F.
A non-iron-based crosslinker has been developed for in-situ high-strength gelled acid systems that vary between 5 to 20 wt% HCl acid. The coreflooding experiments were effectively conducted for permeability ranges of up to 70 md. This system showed a stable fluid at downhole conditions, initially building viscosity between a pH range of 1.5 to 3.0. Then, as acid continues to further react with calcium carbonate and the pH becomes higher than 3, the crosslinked fluid begins to break down and the fluid viscosity decreases. Several experiments were conducted to assess the performance of this novel system. Additionally, corrosion tests were performed to evaluate the treatment fluid corrosion rate at a temperature of 275°F.
The testing results show that the evaluated gelled acid system is stable at temperatures up to 275°F. The system profile as a function of pH showed the ability to provide diversion during different stimulation treatments. Additionally, the coreflood results showed that the new gelled acid is capable of forming wormholes without any significant associated formation damage caused by the gel. The effect of corrosion inhibitors on this system at 300°F, along with other additives, was also investigated.