Accurate information regarding forest volume plays an important role in estimating afforestation, timber harvesting, and forest ecological services. Traditionally, operations on forest growing stock volume using field measurements are labor-intensive and time-consuming. Recently, remote sensing technology has emerged as a time-cost efficient method for forest inventory. In the present study, we have adopted three procedures, including samples expanding, feature selection, and results generation and evaluation. Extrapolating the samples from Light Detection and Ranging (LiDAR) scanning is the most important step in satisfying the requirement of sample size for nonparametric methods operation and result in accuracy improvement. Besides, mean decrease Gini (MDG) methodology embedded into Random Forest (RF) algorithm served as a selector for feature measure; afterwards, RF and K-Nearest Neighbor (KNN) were adopted in subsequent forest volume prediction. The results show that the retrieval of Forest volume in the entire area was in the range of 50–360 m3/ha, and the results from the two models show a better consistency while using the sample combination extrapolated by the optimal threshold value (2 × 10−4), leading to the best performances of RF (R2 = 0.618, root mean square error, RMSE = 43.641 m3/ha, mean absolute error, MAE = 33.016 m3/ha), followed by KNN (R2 = 0.617, RMSE = 43.693 m3/ha, MAE = 32.534 m3/ha). The detailed analysis that is discussed in the present paper clearly shows that expanding image-derived LiDAR samples helps in refining the prediction of regional forest volume while using satellite data and nonparametric models.