Evaluation of the Persistence of Linalool and Estragole in Maize Grains via Headspace Solid-Phase Microextraction and Gas Chromatography

Moura, Elisa Ferreira; Faroni, L. R. D.; Rodrigues, Alessandra Aparecida Zinato; Heleno, Fernanda Fernandes; Queiroz, Maria Eliana Lopes Ribeiro de; Vilela, Ailyn de Oliveira

doi:10.1007/s12161-020-01862-9

Cited by 4 publications

(6 citation statements)

References 75 publications

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“…In some cases, the SPME fiber can be directly exposed to the headspace of a vial containing solid food sample for the extraction of volatile analytes. 102 The food samples can be treated by simple heating to accelerate the volatilization of target analytes. Sweet corn, mopane worms, and peanuts have been roasted at 150 °C before headspace extraction of furan, 103 which has also been effectively extracted from cooked instant noodle samples.…”

Section: ■ Spme In Food Analysismentioning

confidence: 99%

Latest Improvements and Expanding Applications of Solid-Phase Microextraction

et al. 2023

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Section: ■ Spme In Food Analysismentioning

confidence: 99%

Latest Improvements and Expanding Applications of Solid-Phase Microextraction

et al. 2023

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“…The HS-SPME technique (Figure 1), based on previous publications by our research group [14,46,48], was used for the simultaneous determination and quantification of safrole in cowpea beans. Briefly, the assays were performed using a manual SPME holder (Supelco, Bellefont, PA, USA) equipped with a divinylbenzenecarboxen-polydimethylsiloxane-50/30 µm fiber (DVB/CAR/PDMS-50/30 µm) (Supelco, Bellefont, USA).…”

Section: Hs-spme Proceduresmentioning

confidence: 99%

“…Botanical insecticides stand out among options for insect control for being considered safer and non-associated with the development of pest resistance, consequently presenting a lower contamination risk to the environment and human and animal health [12,13]. Among them are the essential oils (EOs), volatile compounds with an intense odor and, in most cases, a lipophilic constitution, derived from the secondary metabolism of plants [14]. Due to their insecticidal activity, EOs and their chemical constituents are promising alternatives for controlling insect pests in stored grains [15].…”

Section: Introductionmentioning

confidence: 99%

“…The criteria for using P. hispidinervum essential oil (PHEO) in stored-grain pest control must consider its post-treatment persistence in the grain mass. Analyses of insecticide persistence are critical to ensuring food security and determining the grace period [14]. Nonetheless, it is remarkable that only a few studies have approached this topic for botanical insecticides applied to stored grains.…”

Section: Introductionmentioning

confidence: 99%

“…The solid-phase microextraction technique (SPME) is widely employed in residue analysis, mostly because it performs both extraction and pre-concentration of analytes simultaneously [14,42,43]. The SPME fiber can be used either in the headspace (HS-SPME) or directly immersed in the sample (DI-SPME).…”

Section: Introductionmentioning

confidence: 99%

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Method Validation and Evaluation of Safrole Persistence in Cowpea Beans Using Headspace Solid-Phase Microextraction and Gas Chromatography

et al. 2021

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Bioinsecticides are regarded as important alternatives for controlling agricultural pests. However, few studies have determined the persistence of these compounds in stored grains. This study aimed at optimizing and validating a fast and effective method for extraction and quantification of residues of safrole (the main component of Piper hispidinervum essential oil) in cowpea beans. It also sought to assess the persistence of this substance in the grains treated by contact and fumigation. The proposed method used headspace solid-phase microextraction (HS-SPME) and gas chromatography with a flame ionization detector (GC/FID). Factors such as temperature, extraction time and type of fiber were assessed to maximize the performance of the extraction technique. The performance of the method was appraised via the parameters selectivity, linearity, limit of detection (LOD), limit of quantification (LOQ), precision, and accuracy. The LOD and LOQ of safrole were 0.0057 and 0.019 μg kg−1, respectively and the determination coefficient (R2) was >0.99. The relative recovery ranged from 99.26 to 104.85, with a coefficient of variation <15%. The validated method was applied to assess the persistence of safrole residue in grains, where concentrations ranged from 1.095 to 0.052 µg kg−1 (contact) and from 2.16 to 0.12 µg kg −1 (fumigation). The levels measured up from the fifth day represented less than 1% of the initial concentration, proving that safrole have low persistence in cowpea beans, thus being safe for bioinsecticide use. Thus, this work is relevant not only for the extraction method developed, but also for the possible use of a natural insecticide in pest management in stored grains.

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Headspace Microextraction. A Comprehensive Review on Method Application to the Analysis of Real Samples (from 2018 till Present)

Skok,

Bazel

2023

Critical Reviews in Analytical Chemistry

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Evaluation of the Persistence of Linalool and Estragole in Maize Grains via Headspace Solid-Phase Microextraction and Gas Chromatography

Cited by 4 publications

References 75 publications

Latest Improvements and Expanding Applications of Solid-Phase Microextraction

Latest Improvements and Expanding Applications of Solid-Phase Microextraction

Method Validation and Evaluation of Safrole Persistence in Cowpea Beans Using Headspace Solid-Phase Microextraction and Gas Chromatography

Headspace Microextraction. A Comprehensive Review on Method Application to the Analysis of Real Samples (from 2018 till Present)

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